Gadolinium Effect at High-Magnetic-Field DNP: 70% 13C Polarization of [U-13C] Glucose Using Trityl

Author:

Capozzi Andrea1ORCID,Patel Saket1,Wenckebach W. Thomas23,Karlsson Magnus1,Lerche Mathilde H.1,Ardenkjær-Larsen Jan Henrik14ORCID

Affiliation:

1. Center for Hyperpolarization in Magnetic Resonance, Department of Health Technology, Technical University of Denmark, Building 349, 2800 Kongens Lyngby, Denmark

2. Paul Scherrer Institute, CH-5232 Villigen, Switzerland

3. National High Magnetic Field Laboratory, UF, AMRIS, Gainesville, Florida 32611, United States

4. GE Healthcare, Park Alle 295, 2605 Brøndby, Denmark

Funder

Danmarks Grundforskningsfond

H2020 Marie Sklodowska-Curie Actions

Publisher

American Chemical Society (ACS)

Subject

General Materials Science,Physical and Theoretical Chemistry

Reference33 articles.

1. Increase in signal-to-noise ratio of > 10,000 times in liquid-state NMR

2. NMR Insights into the Inner Workings of Living Cells

3. Principles of dynamic nuclear polarisation

4. Discussion of other polarizing agents such as BDPA and TEMPO is beyond the scope of the present manuscript. To avoid confusion, we specify that all data, observations, and comments taken from the literature are limited to the case of trityl.

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