Femtosecond X-ray Spectroscopy Directly Quantifies Transient Excited-State Mixed Valency

Author:

Liekhus-Schmaltz Chelsea1,Fox Zachary W.1,Andersen Amity2ORCID,Kjaer Kasper S.34,Alonso-Mori Roberto5,Biasin Elisa3ORCID,Carlstad Julia1,Chollet Matthieu5,Gaynor James D.1ORCID,Glownia James M.5,Hong Kiryong6ORCID,Kroll Thomas7,Lee Jae Hyuk6,Poulter Benjamin I.1,Reinhard Marco3,Sokaras Dimosthenis7,Zhang Yu8,Doumy Gilles9ORCID,March Anne Marie9ORCID,Southworth Stephen H.9,Mukamel Shaul8ORCID,Cordones Amy A.3ORCID,Schoenlein Robert W.35,Govind Niranjan10ORCID,Khalil Munira1ORCID

Affiliation:

1. Department of Chemistry, University of Washington, Seattle, Washington 98195, United States

2. Environmental Molecular Sciences Laboratory, Earth and Biological Sciences Directorate, Pacific Northwest National Laboratory, Richland, Washington 99352, United States

3. Stanford PULSE Institute, SLAC National Accelerator Laboratory, Menlo Park, California 94025, United States

4. Department of Physics, Technical University of Denmark, 2800 Kongens Lyngby, Denmark

5. Linac Coherent Light Source, SLAC National Accelerator Laboratory, Menlo Park, California 94025, United States

6. Ultrafast X-ray Science Laboratory, Chemical Sciences Division, Lawrence Berkeley National Laboratory, Berkeley, California 94720, United States

7. SSRL, SLAC National Accelerator Laboratory, Menlo Park, California 94025, United States

8. Department of Chemistry and Department of Physics & Astronomy, University of California, Irvine, California 94025, United States

9. Chemical Sciences and Engineering Division, Argonne National Laboratory, Lemont, Illinois 60439, United States

10. Physical Sciences Division, Physical and Computational Sciences Directorate, Pacific Northwest National Laboratory, Richland, Washington 99352, United States

Funder

U.S. Department of Energy

National Science Foundation

Publisher

American Chemical Society (ACS)

Subject

General Materials Science,Physical and Theoretical Chemistry

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