Onium Transfer Reaction of (β,β-Dialkylvinyl)(phenyl)iodonium Tetrafluoroborates via an Alkylidene Carbene Pathway: Synthesis of Group 15 Alkenyl(triphenyl)- and Group 16 Alkenyl(diphenyl)onium Salts-Reference-Cited by-同舟云学术

Onium Transfer Reaction of (β,β-Dialkylvinyl)(phenyl)iodonium Tetrafluoroborates via an Alkylidene Carbene Pathway: Synthesis of Group 15 Alkenyl(triphenyl)- and Group 16 Alkenyl(diphenyl)onium Salts

Published:1999-10-22 Issue:23 Volume:64 Page:8563-8567
ISSN:0022-3263
Container-title:The Journal of Organic Chemistry
language:en
Short-container-title:J. Org. Chem.

Author:

Ochiai Masahito¹,Sueda Takuya¹,Noda Rie¹,Shiro Motoo¹

Affiliation:

1. Faculty of Pharmaceutical Sciences, University of Tokushima, 1-78 Shomachi, Tokushima 770-8505, and Rigaku Corporation, 3-9-12 Matsubara, Akishima, Tokyo 196, Japan

Publisher

American Chemical Society (ACS)

Subject

Organic Chemistry

Link

https://pubs.acs.org/doi/pdf/10.1021/jo990963k

Reference33 articles.

1. Hypervalent alkenyliodonium tetrafluoroborates. Evidence for generation of alkylidenecarbenes via base-induced .alpha.-elimination

2. Generation of [.beta.-(phenylsulfonyl)alkylidene]carbenes from hypervalent alkenyl- and alkynyliodonium tetrafluoroborates and synthesis of 1-(phenylsulfonyl)cyclopentenes

3. Solvolysis of Cyclohexenyliodonium Salt, a New Precursor for the Vinyl Cation: Remarkable Nucleofugality of the Phenyliodonio Group and Evidence for Internal Return from an Intimate Ion-Molecule Pair

4. Evidence for Reversible Ylide Formation: Equilibrium between Free Alkylidenecarbenes and Ethereal Solvent−Alkylidenecarbene Complexes (Oxonium Ylides)

5. Nature of Alkylidenecarbenes Generated from Alkenylphenyliodonium Tetrafluoroborates via Base-Induced .alpha.-Elimination

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