Fast Rotational Dynamics in Argyrodite-Type Li6PS5X (X: Cl, Br, I) as Seen by 31P Nuclear Magnetic Relaxation—On Cation–Anion Coupled Transport in Thiophosphates
Author:
Affiliation:
1. Institute for Chemistry and Technology of Materials (NAWI Graz), and Christian Doppler Laboratory for Lithium Batteries, Graz University of Technology, Stremayrgasse 9, A-8010 Graz, Austria
Funder
Horizon 2020 Framework Programme, European Union
Publisher
American Chemical Society (ACS)
Subject
Materials Chemistry,General Chemical Engineering,General Chemistry
Link
http://pubs.acs.org/doi/pdf/10.1021/acs.chemmater.9b01435
Reference37 articles.
1. Li6PS5X: A Class of Crystalline Li-Rich Solids With an Unusually High Li+ Mobility
2. Highly Mobile Ions: Low-Temperature NMR Directly Probes Extremely Fast Li+ Hopping in Argyrodite-Type Li6PS5Br
3. Influence of Lattice Polarizability on the Ionic Conductivity in the Lithium Superionic Argyrodites Li6PS5X (X = Cl, Br, I)
4. Inducing High Ionic Conductivity in the Lithium Superionic Argyrodites Li6+xP1–xGexS5I for All-Solid-State Batteries
5. A lithium argyrodite Li6PS5Cl0.5Br0.5 electrolyte with improved bulk and interfacial conductivity
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