Particle Size Is a Primary Determinant for Sigmoidal Kinetics of Nanoparticle Formation: A “Disproof” of the Finke–Watzky (F-W) Nanoparticle Nucleation and Growth Mechanism
Author:
Affiliation:
1. Department of Chemistry, North Carolina State University, Raleigh, North Carolina 27695-8204, United States
Funder
Division of Materials Research
Publisher
American Chemical Society (ACS)
Subject
Materials Chemistry,General Chemical Engineering,General Chemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/acs.chemmater.9b02839
Reference20 articles.
1. Transition Metal Nanocluster Formation Kinetic and Mechanistic Studies. A New Mechanism When Hydrogen Is the Reductant: Slow, Continuous Nucleation and Fast Autocatalytic Surface Growth
2. A Mechanism for Transition-Metal Nanoparticle Self-Assembly
3. Nanocluster nucleation and growth kinetic and mechanistic studies: A review emphasizing transition-metal nanoclusters
4. Transition-Metal Nanocluster Size vs Formation Time and the Catalytically Effective Nucleus Number: A Mechanism-Based Treatment
5. Fitting and Interpreting Transition-Metal Nanocluster Formation and Other Sigmoidal-Appearing Kinetic Data: A More Thorough Testing of Dispersive Kinetic vs Chemical-Mechanism-Based Equations and Treatments for 4-Step Type Kinetic Data
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