A Radical Cascade Cyclization To Prepare Dihydrothiophenes Induced by Thiyl Radicals as Sulfur Biradical Equivalents

Author:

Kamimura Akio1,Miyazaki Koichiro1,Yamane Yu1,Yo Ryuichiro1,Ishikawa Shingo1,Uno Hidemitsu2,Sumimoto Michinori3

Affiliation:

1. Department of Applied Molecular Science, Graduate School of Medicine, Yamaguchi University, Ube 755-8611, Japan

2. Department of Chemistry, Graduate School of Science and Engineering, Ehime University, Matsuyama 790-8577, Japan

3. Department of Material Chemistry, Graduate School of Science and Engineering, Yamaguchi University, Ube 755-8611, Japan

Publisher

American Chemical Society (ACS)

Subject

Organic Chemistry

Reference39 articles.

1. aZimmerman, J.; Halloway, A.; Sibi, M. P.InHandbook of Cyclization Reactions;Ma, S., Ed.Wiley-VCH:Weinheim, 2010; Vol. 2, pp 1099–1148; Yoshioka, E.; Kohtani, S.; Miyabe, H. Heterocycles, 2009, 79, 229.

2. Radicals in organic synthesis: part 2

3. Controlling the regiochemistry of radical cyclizations

4. Formation of five- and six-membered heterocyclic rings under radical cyclisation conditions

5. Titanocene‐Mediated Radical Cyclization: An Emergent Method Towards the Synthesis of Natural Products

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