Multiple Mechanistic Pathways for Zirconium-Catalyzed Carboalumination of Alkynes. Requirements for Cyclic Carbometalation Processes Involving C−H Activation-Reference-Cited by-同舟云学术

Multiple Mechanistic Pathways for Zirconium-Catalyzed Carboalumination of Alkynes. Requirements for Cyclic Carbometalation Processes Involving C−H Activation

Published:1996-01-01 Issue:40 Volume:118 Page:9577-9588
ISSN:0002-7863
Container-title:Journal of the American Chemical Society
language:en
Short-container-title:J. Am. Chem. Soc.

Author:

Negishi Ei-ichi¹,Kondakov Denis Y.¹,Choueiry Danièle¹,Kasai Kayoko¹,Takahashi Tamotsu¹

Affiliation:

1. Contribution from the Department of Chemistry, Purdue University, West Lafayette, Indiana 47907, and the Institute for Molecular Science, Myodaiji, Okazaki 444, Japan

Publisher

American Chemical Society (ACS)

Subject

Colloid and Surface Chemistry,Biochemistry,General Chemistry,Catalysis

Link

https://pubs.acs.org/doi/pdf/10.1021/ja9538039

Reference40 articles.

1. Selective carbon-carbon bond formation via transition metal catalysts. 8. Controlled carbometalation. Reaction of acetylenes with organoalane-zirconocene dichloride complexes as a route to stereo- and regio-defined trisubstituted olefins

2. Controlled carbometalation. 20. Carbometalation reaction of alkynes with organoalene-zirconocene derivatives as a route to stereo-and regiodefined trisubstituted alkenes

3. Bimetallic catalytic systems containing Ti, Zr, Ni, and Pd. Their applications to selective organic syntheses

4. Controlled carbometallation

5. Mechanism of the zirconium-catalyzed carboalumination of alkynes. Evidence for direct carboalumination

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