(Phosphinoalkyl)silanes. 3.1 Poly(o-(diphenylphosphino)benzyl)silanes: Synthesis, Spectroscopic Properties, and Complexation at Platinum or Iridium
Author:
Affiliation:
1. Department of Chemistry, University of Victoria, Victoria, British Columbia, Canada V8W 2Y2
Publisher
American Chemical Society (ACS)
Subject
Inorganic Chemistry,Physical and Theoretical Chemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/ic941230f
Reference10 articles.
1. (Phosphinoalkyl)silanes. 2. Synthesis and spectroscopic properties of the poly(phosphinoalkyl)silanes SiHR[(CH2)nPR'2]2 (R = Me or Ph; n = 2 or 3; R' = Ph or cyclohexyl) and SiH[(CH2)nPR'2]3 (R = Me or Ph; n = 2, R' = Ph or cyclohexyl; n = 3, R' = Ph)
2. Phosphinoalkylsilanes: synthesis and spectroscopic properties of phosphino(silyl)methanes, 1-phosphino-2-silylethanes, and 1-phosphino-3-silylpropanes
3. (Phosphinoalkyl)silyl complexes. 5. Synthesis and reactivity of congeneric chelate-stabilized disilyl complexes of rhodium(III) and iridium(III): chlorobis[[(diphenylphosphino)ethyl]dimethylsilyl]rhodium and -iridium
4. (Phosphinoalkyl)silyl complexes. 3. "Chelate-assisted" hydrosilylation: formation of enantiomeric and diastereoisomeric iridium(III) complexes with chelating (phosphinoethyl)silyl ligands
5. Synthesis and structure of a silyl–rhodium(I) complex: stabilization attributable to multisite ‘anchoring’ of a silyl fragment
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