Iodine (I2) as a Janus-Faced Ligand in Organometallics
Author:
Affiliation:
1. Baker Laboratory, Department of Chemistry and Chemical Biology, Cornell University, Ithaca, New York 14853, United States
Publisher
American Chemical Society (ACS)
Subject
Colloid and Surface Chemistry,Biochemistry,General Chemistry,Catalysis
Link
https://pubs.acs.org/doi/pdf/10.1021/ja312584u
Reference55 articles.
1. Models for the Initial Stages of Oxidative Addition. Synthesis, Characterization, and Mechanistic Investigation of η1-I2 Organometallic “Pincer” Complexes of Platinum. X-ray Crystal Structures of [PtI(C6H3{CH2NMe2}2-2,6)(η1-I2)] and exo-meso-[Pt(η1-I3)(η1-I2)(C6H3{CH2N(t-Bu)Me}2-2,6)]
2. Model for the initial stage in the oxidative addition of I2 to organoplatinum(II) compounds. X-ray structure of square-pyramidal [PtIII{C6H3(CH2NMe2)2-o,o'}(.eta.1-I2)] containing a linear Pt-I-I arrangement
3. Synthesis and reactivity towards diiodine of palladium(II) and platinum(II) complexes with non-cyclic and cyclic ligands (C6H3{CH2NR1R2}2-2,6)−. End-on diiodine-platinum(II) bonding in macrocyclic [PtI(C6H3{CH2NMe(CH2)7MeNCH2}-2,6)(η1-I2)]
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1. Computational Study of Equilibria Formed by Diiodine (I2) and the Pincer Complex [2,6‐bis{(Me2NCH2)2}C6H3]PtIII: Intramolecular Mobility of I2 Using ′Pt‐I2′, ′Pt‐I ⋅ ⋅ ⋅ I2′ and ′Cpara ⋅ ⋅ ⋅ I2′ Species;European Journal of Inorganic Chemistry;2024-07-18
2. C@MOF composite material for rapid and efficient capture of gaseous iodine;Chemical Engineering Journal;2024-06
3. Design monolayer iodinenes based on halogen bond and tiling theory;Physical Review B;2024-03-20
4. Structures and stability of I2 and ICl complexes with pyridine: Ab initio and DFT study;Journal of Computational Chemistry;2024-01-02
5. Stability of Molecular Complexes of Iodine and Iodine Monochloride with Nitrogen-Containing Donors;Russian Journal of General Chemistry;2024-01
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