Cleavage of H−C(sp2) and C(sp2)−X Bonds (X = Alkyl, Aryl, OR, NR2): Facile Decarbonylation, Isonitrile Abstraction, or Dehydrogenation of Aldehydes, Esters, Amides, Amines, and Imines by [RuHCl(PiPr3)2]2
Author:
Affiliation:
1. Department of Chemistry, Indiana University, Bloomington, Indiana 47405-7102
Publisher
American Chemical Society (ACS)
Subject
Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/om000390y
Reference16 articles.
1. Coordinated carbenes from electron-rich olefins on RuHCl(PPr3i)2
2. 14-Electron Four-Coordinate Ru(II) Carbyl Complexes and Their Five-Coordinate Precursors: Synthesis, Double Agostic Interactions, and Reactivity
3. Acid−Base Control of a Migratory Insertion Reaction: p-Aminophenyl Derivatives of Ruthenium(II) and the Crystal Structure of Ru(η2-C[O]C6H4NH2-4)Cl(CO)(PPh3)2
4. Carbamoyl (Carboxamido) Complexes as Precursors for Metallaoxetene, Isonitrile, and Aminomethylidyne Complexes of Iron
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