Thermodynamic and Kinetic Studies of H Atom Transfer from HMo(CO)3(η5-C5H5) to Mo(N[t-Bu]Ar)3 and (PhCN)Mo(N[t-Bu]Ar)3: Direct Insertion of Benzonitrile into the Mo−H Bond of HMo(N[t-Bu]Ar)3 forming (Ph(H)C═N)Mo(N[t-Bu]Ar)3-Reference-Cited by-同舟云学术

Thermodynamic and Kinetic Studies of H Atom Transfer from HMo(CO)3(η5-C5H5) to Mo(N[t-Bu]Ar)3 and (PhCN)Mo(N[t-Bu]Ar)3: Direct Insertion of Benzonitrile into the Mo−H Bond of HMo(N[t-Bu]Ar)3 forming (Ph(H)C═N)Mo(N[t-Bu]Ar)3

Published:2008-09-13 Issue:20 Volume:47 Page:9380-9389
ISSN:0020-1669
Container-title:Inorganic Chemistry
language:en
Short-container-title:Inorg. Chem.

Author:

Temprado Manuel¹,McDonough James Eric¹,Mendiratta Arjun¹,Tsai Yi-Chou¹,Fortman George C.¹,Cummins Christopher C.¹,Rybak-Akimova Elena V.¹,Hoff Carl D.¹

Affiliation:

1. Department of Chemistry, Massachusetts Institute of Technology, 77 Massachusetts Avenue, Cambridge, Massachusetts 02139, Department of Chemistry, Tufts University, 62 Talbot Avenue, Medford, Massachusetts, 02155, and Department of Chemistry, University of Miami, 1301 Memorial Drive, Coral Gables, Florida, 33146

Publisher

American Chemical Society (ACS)

Subject

Inorganic Chemistry,Physical and Theoretical Chemistry

Link

https://pubs.acs.org/doi/pdf/10.1021/ic800945m

Reference65 articles.

1. Benzonitrile Extrusion from Molybdenum(IV) Ketimide Complexes Obtained via Radical C−E (E = O, S, Se) Bond Formation: Toward a New Nitrogen Atom Transfer Reaction

2. The Niobaziridine−Hydride Functional Group: Synthesis and Divergent Reactivity

3. Generation and Reactivity of CpW(NO)(CH2SiMe3)H, a 16-Valence-Electron Alkyl Hydride Complex

4. Systematic Studies of Early Actinide Complexes: Thorium(IV) Fluoroketimides

5. Systematic Studies of Early Actinide Complexes: Uranium(IV) Fluoroketimides

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