Asymmetric Synthesis of P-Stereogenic Homo- and Heterobimetallic Complexes via Selective Monoinsertion of Dialkynylphosphine into the Pd−C Bond of a Palladacycle
Author:
Affiliation:
1. Division of Chemistry & Biological Chemistry, School of Physical & Mathematical Sciences, Nanyang Technological University, Singapore 637371
Publisher
American Chemical Society (ACS)
Subject
Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/om101078p
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3. Synthesis of a Novel α-Diimine Palladium(II) Complex Bearing an η3-Allyl γ-Lactone Ligand, a Key Intermediate in Alkyne Cyclocarbonylation Processes
4. Reactivity of Ortho-Palladated Phenol Derivatives with Unsaturated Molecules. 1. Insertion of CO, Isocyanides, Alkenes, and Alkynes. CO/Alkene, Alkyne/Isocyanide, and Isocyanide/Alkene Sequential Insertion Reactions
5. Structurally characterized intermediates in the stepwise insertion of CO–ethylene or CO–methyl acrylate into the metal–carbon bond of Pd(ii) complexes stabilized by (phosphinomethyl)oxazoline ligands
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1. A one-pot process for synthesis of eight-membered cyclopalladated amidines via cascade C H activation and insertion;Journal of Organometallic Chemistry;2020-10
2. C–H Activation in Primary 3-Phenylpropylamines: Synthesis of Seven-Membered Palladacycles through Orthometalation. Stoichiometric Preparation of Benzazepinones and Catalytic Synthesis of Ureas;Inorganic Chemistry;2016-05-09
3. Recent Advances in Asymmetric Synthesis of Р-Stereogenic Phosphorus Compounds;Topics in Current Chemistry;2014
4. Reactivity of Eight-Membered Palladacycles Arising from Monoinsertion of Alkynes into the Pd–C bond of Ortho-Palladated Phenethylamines toward Unsaturated Molecules. Synthesis of Dihydro-3-Benzazocinones, N7-amino Acids, N7-amino Esters, and 3-Benzazepines;Organometallics;2013-12-13
5. Stability and Reactivity of Cyclometallated Naphthylamine Complexes in Pd–C Bond Insertion Reactions with Coordinated Alkynylphosphanes;European Journal of Inorganic Chemistry;2013-09-17
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