Synthesis of Biomimetic Heme Precursors: The “Double Picket Fence” 5,10,15,20-Tetrakis(2‘,6‘- dinitro-4‘-tert-butylphenyl)porphyrin
Author:
Affiliation:
1. Laboratoire de Synthèse Organique et Organométallique URA CNRS 408, Tour 44, 4 Place Jussieu 75230 Paris Cedex 05, France
Publisher
American Chemical Society (ACS)
Subject
Colloid and Surface Chemistry,Biochemistry,General Chemistry,Catalysis
Link
https://pubs.acs.org/doi/pdf/10.1021/ja952580j
Reference21 articles.
1. Synthetic Heme-Dioxygen Complexes
2. Regioselective and enantioselective epoxidation catalyzed by metalloporphyrins
3. Picket fence porphyrins. Synthetic models for oxygen binding hemoproteins
4. In the literature, two groups described at approximatively the same time the condensation of 2,6-dinitrobenzaldehyde and pyrrole (0.75% yield with CF3CO2H as catalyst4and 2-13% yield with BF3·OEt2as catalyst).5We and others6were unfortunately not able to reproduce the preparation of these interesting 5,10,15,20-tetrakis(2‘,6‘-dinitro- and -diaminophenyl)porphyrins.6
5. Synthesis and characterization of copper(II) 5,10,15,20-tetrakis(2,6-dipivalamidophenyl)porphyrinate: a bis-picket-fence porphyrin
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