Metal and Ligand Effects on Coordinated Methane pKa: Direct Correlation with the Methane Activation Barrier
Author:
Affiliation:
1. Department of Chemistry Center for Advanced Scientific Computing and Modeling (CASCaM), University of North Texas, Denton, Texas 76203-5070, United States
Funder
Division of Chemistry
Publisher
American Chemical Society (ACS)
Subject
Physical and Theoretical Chemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/acs.jpca.0c04756
Reference15 articles.
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2. Activation of C−H Bonds by Metal Complexes
3. Selective functionalization of methane, ethane, and higher alkanes by cerium photocatalysis
4. Chemistry in super acids. I. Hydrogen exchange and polycondensation of methane and alkanes in FSO3H-SbF5 ("magic acid") solution. Protonation of alkanes and the intermediacy of CH5+ and related hydrocarbon ions. The high chemical reactivity of "paraffins" in ionic solution reactions
5. Kinetic acidity of methane
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