Conformational Landscape of α-Halopropiophenones Determined by nJC–H NMR Reveals Unexpected Patterns and Geometric Constraints-Reference-Cited by-同舟云学术

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Conformational Landscape of α-Halopropiophenones Determined by ⁿJ_C–H NMR Reveals Unexpected Patterns and Geometric Constraints

Published:2024-02-27 Issue:9 Volume:128 Page:1566-1575
ISSN:1089-5639
Container-title:The Journal of Physical Chemistry A
language:en
Short-container-title:J. Phys. Chem. A

Author:

Francisco Camila Botin¹²,Fernandes Cleverton de Souza¹,Franco Dourado Fernanda¹^ORCID,Gauze Gisele de Freitas¹,Rittner Roberto³,Prosser Robert Scott²^ORCID,Basso Ernani Abicht¹^ORCID

Affiliation:

1. Department of Chemistry, State University of Maringá, 5790, Maringá 87020-900, Brazil

2. Department of Chemistry, University of Toronto, 3359, Mississauga L5L-1C6, Canada

3. Chemistry Institute, University of Campinas, 6154, Campinas 13083-970, Brazil

Funder

Conselho Nacional de Desenvolvimento Cient?fico e Tecnol?gico

Coordena??o de Aperfei?oamento de Pessoal de N?vel Superior

Publisher

American Chemical Society (ACS)

Link

https://pubs.acs.org/doi/pdf/10.1021/acs.jpca.3c06934

Reference23 articles.

1. Hyperconjugation

2. Hyperconjugation not steric repulsion leads to the staggered structure of ethane

3. Stereoelectronic Effects and General Trends in Hyperconjugative Acceptor Ability of σ Bonds

4. Iodine Gauche Effect Induced by an Intramolecular Hydrogen Bond

5. Competitive resonance at the carbonyl group as visualized by the natural bond orbital analysis

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