Temperature Dependence of Nuclear Quadrupole Resonance and the Observation of Metal–Ligand Covalency in Actinide Complexes: 35Cl in Cs2UO2Cl4-Reference-Cited by-同舟云学术

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Temperature Dependence of Nuclear Quadrupole Resonance and the Observation of Metal–Ligand Covalency in Actinide Complexes: ³⁵Cl in Cs₂UO₂Cl₄

Published:2023-09-28 Issue:40 Volume:127 Page:8347-8353
ISSN:1089-5639
Container-title:The Journal of Physical Chemistry A
language:en
Short-container-title:J. Phys. Chem. A

Author:

Park Sejun¹^ORCID,Walter Eric D.²^ORCID,Soderquist Chuck Z.³^ORCID,Sinkov Sergey I.³,Cho Herman¹^ORCID

Affiliation:

1. Physical and Computational Sciences Directorate, Pacific Northwest National Laboratory, Richland, Washington 99354, United States

2. Environmental Molecular Sciences Laboratory, Pacific Northwest National Laboratory, Richland, Washington 99354, United States

3. Energy and Environment Directorate, Pacific Northwest National Laboratory, Richland, Washington 99354, United States

Funder

Chemical Sciences, Geosciences, and Biosciences Division

Publisher

American Chemical Society (ACS)

Subject

Physical and Theoretical Chemistry

Link

https://pubs.acs.org/doi/pdf/10.1021/acs.jpca.3c04657

Reference60 articles.

1. The electronic structure of actinide-containing molecules: a challenge to applied quantum chemistry

2. Kaltsoyannis, N.; Hay, P. J.; Li, J.; Blaudeau, J.P.; Bursten, B. E. The Chemistry of the Actinide and Transactinide Elements, 4th ed. Morss, L. R.; Edelstein, N. M.; Fuger, J., Eds. Springer: Netherlands, 2006; Vol. 3, Chapter 17, pp 1893–2012.

3. Does Covalency Increase or Decrease across the Actinide Series? Implications for Minor Actinide Partitioning

4. Ligand K-edge X-ray absorption spectroscopy: covalency of ligand–metal bonds

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