Novel High-Yield Method for the Synthesis of [Os3(CO)10(μ-H)(μ-OSiR2R‘)] Species and X-ray Characterization of [Os3(CO)10(μ-H)(μ-OSiPh2OSiPh2OH)] and [Os3(CO)10(μ-H)(μ-OSiPh2OH)], First Molecular Models of Osmium Surface Species Anchored to Vicinal and Geminal Surface Silanols-Reference-Cited by-同舟云学术

Novel High-Yield Method for the Synthesis of [Os3(CO)10(μ-H)(μ-OSiR2R‘)] Species and X-ray Characterization of [Os3(CO)10(μ-H)(μ-OSiPh2OSiPh2OH)] and [Os3(CO)10(μ-H)(μ-OSiPh2OH)], First Molecular Models of Osmium Surface Species Anchored to Vicinal and Geminal Surface Silanols

Published:2000-02-18 Issue:6 Volume:19 Page:1051-1059
ISSN:0276-7333
Container-title:Organometallics
language:en
Short-container-title:Organometallics

Author:

Lucenti Elena¹,Roberto Dominique¹,Roveda Carmen¹,Ugo Renato¹,Sironi Angelo²

Affiliation:

1. Dipartimento di Chimica Inorganica, Metallorganica e Analitica and Centro CNR “CSSSCMTBSO”, Università di Milano, Via G. Venezian, 21, 20133 Milano, Italy

2. Dipartimento di Chimica Strutturale e Stereochimica Inorganica and Centro CNR “CSSSCMTBSO”, Università di Milano, Via G. Venezian, 21, 20133 Milano, Italy

Publisher

American Chemical Society (ACS)

Subject

Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry

Link

https://pubs.acs.org/doi/pdf/10.1021/om9908074

Reference55 articles.

1. I.r. and E.X.A.F.S. characterisation of a supported osmium cluster carbonyl

2. Surface supported metal cluster carbonyls. the surface organometallic chemistry of polymetallic and monometallic osmium carbonyl species formed by depositing various osmium clusters on silica and alumina

3. Surface-supported metal cluster carbonyls. Chemisorption, decomposition and reactivity of Os3(CO)12, H2Os3(CO)10 and Os6(CO)18 supported on silica and alumina and the investigation of the fischer-tropsch catalysis with these systems

4. Surface organometallic chemistry: A new approach to heterogeneous Catal.ysis ?

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