Syntheses, Structural Determinations of [Ru(ROCS2)2(PPh3)2]+/0 Pairs, and Kinetic Analyses of Thermal Reactions Involving Transient trans-[Ru(iPrOCS2)2(PPh3)2] Species (ROCS2- = Ethyl- or Isopropyldithiocarbonate and PPh3 = Triphenylphosphine)-Reference-Cited by-同舟云学术

Syntheses, Structural Determinations of [Ru(ROCS2)2(PPh3)2]+/0 Pairs, and Kinetic Analyses of Thermal Reactions Involving Transient trans-[Ru(iPrOCS2)2(PPh3)2] Species (ROCS2- = Ethyl- or Isopropyldithiocarbonate and PPh3 = Triphenylphosphine)

Published:2006-01-12 Issue:3 Volume:45 Page:1349-1355
ISSN:0020-1669
Container-title:Inorganic Chemistry
language:en
Short-container-title:Inorg. Chem.

Author:

Noda Kyoko¹,Ohuchi Yuko¹,Hashimoto Akira¹,Fujiki Masayuki¹,Itoh Sumitaka¹,Iwatsuki Satoshi¹,Noda Toshiaki¹,Suzuki Takayoshi¹,Kashiwabara Kazuo¹,Takagi Hideo D.¹

Affiliation:

1. Graduate School of Science and Research Center for Materials Science, Nagoya University, Furocho, Chikusa, Nagoya 464-8602, Japan, Department of Chemistry, Waseda University, Ookubo, Shinjuku 169-8555, Japan, and Department of Chemistry, Graduate School of Science, Osaka University, Toyonaka 560-0043, Japan

Publisher

American Chemical Society (ACS)

Subject

Inorganic Chemistry,Physical and Theoretical Chemistry

Link

https://pubs.acs.org/doi/pdf/10.1021/ic051487l

Reference28 articles.

1. Preparation, crystal structures and isomerization kinetics of cis- and trans-[Co(dtc)2(PHPh2)2]+: thermodynamically and kinetically stable cobalt(iii)–P bonds through interplay of σ-donicity, π-acidity, and steric bulkiness

2. Syntheses, crystal structures and isomerization kinetics of a series of [Co(dtc)2{P(OMe)3 − nPhn}2]+(n = 0–2) complexes (dtc−= N,N-dimethyldithiocarbamate): role of σ-donicity, π-acidity, and cone angle of the P-ligands in the trans influence and trans effect

3. Quantitative analysis of ligand effects. Part 3. Separation of phosphorus(III) ligands into pure .sigma.-donors and .sigma.-donor/.pi.-acceptors. Comparison of basicity and .sigma.-donicity

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