Novel Anionic Oligomerization by a New, Sequential Generation of Organolithium Compounds

Author:

Maruoka Keiji1,Oishi Masataka1,Yamamoto Hisashi1

Affiliation:

1. School of Engineering, Nagoya University, Chikusa, Nagoya 464-01, Japan

Publisher

American Chemical Society (ACS)

Subject

Materials Chemistry,Inorganic Chemistry,Polymers and Plastics,Organic Chemistry

Reference6 articles.

1. Muller, R. K.; Joos, R.; Felix, D.; Schreiber, J.; Wintner, C.; Eschenmoser, A.OrganicSynthesis; Wiley:  New York, 1988; Collect. Vol. VI, p 56.

2. 521. The copper-catalysed decomposition of aliphatic diazo-compounds: the formation of paraffins of high molecular weight

3. 1H NMR (300 MHz, CDCl3):  δ 6.36−7.64 (Ph−H), 0.47−3.05 (2CH2, CH, and But);13C NMR (75 MHz, C6D6at 70 °C) δ 143.7 (ipso-C), 127.6−130.0 (ortho-C,meta-C), 126.5 (para-C), 28.0−51.5 (2CH, CH, and But); IR (KBr) 3025, 2932, 1603, 1495, 1453, 1075, 1030, 907, 749, 698 cm-1. Anal. Calcd for (C9H10)n:  C, 91.47; H, 8.53. Found:  C, 91.68; H, 8.32.

4. Reductive alkylation of aldehyde tosylhydrazones with organolithium reagents

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