Structural and Redox Properties of Novel Spirocyclic 1-Sila-3-ferracyclobutanes, [(η5-C5H4)Fe(L2)CH2SiMe2], L2 = P−P (diphosphine)-Reference-Cited by-同舟云学术

Structural and Redox Properties of Novel Spirocyclic 1-Sila-3-ferracyclobutanes, [(η5-C5H4)Fe(L2)CH2SiMe2], L2 = P−P (diphosphine)

Published:2007-05-04 Issue:12 Volume:26 Page:3005-3009
ISSN:0276-7333
Container-title:Organometallics
language:en
Short-container-title:Organometallics

Author:

Kumar Mukesh¹,Cervantes-Lee Francisco¹,Sharma Hemant K.¹,Pannell Keith H.¹

Affiliation:

1. Department of Chemistry, University of Texas at El Paso Texas, El Paso, Texas 79968-0513

Publisher

American Chemical Society (ACS)

Subject

Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry

Link

https://pubs.acs.org/doi/pdf/10.1021/om061141y

Reference33 articles.

1. (a) Sharma, H. K.; Pannell, K. H. InMetal-Containing and MetalloSupramolecular Polymers and Materials; Schubert, U. S.; Newkome, G. R., Manners, I., Eds.; Oxford University Press: Washington, DC, 2006; p 457.

2. 1-Metalla-3-silacyclobutanes. Synthesis and characterization of [cyclic] (.eta.5-C5H5)2M[CH2Si(CH3)2CH2], M = Ti, Zr, Nb, and Mo

3. Stereochemical influence of the metal orbital occupancy on the structure of the 4-metalla-2-silacyclobutane ring in [cyclic] (.eta.5-C5H5)2M(CH2Si(CH3)2CH2), M = Zr, Nb, and Mo

4. Zirconium-induced lateral insertion of a formaldehyde unit into a 3-zircona-1-silacyclobutane ring. Structural characterization of [cyclic](.eta.5-C5H5)2Zr(OCH2CH2SiMe2CH2)

5. Reactivity studies of the zirconium-induced insertion of isonitriles into a 1-sila-3-zirconacyclobutane ring. Structural and chemical evidence of carbenium-like intermediates for the intramolecular 1,2-silyl shift and reductive coupling reactions

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