1. Department of Inorganic, Physical and Materials Chemistry, and NIS “Center of Excellence”, University of Torino, Via P. Giuria 7, I-10125 Torino Italy, ESRF, BP220 F-38043 Grenoble, France, CNR-INFM-OGG c/o ESRF, Gilda CRG, 6 Rue Jules Horowits F-38043 Grenoble, France, and Schuit Institute of Catalysis, Eindhoven University of Technology, 5600 MB Eindhoven, The Netherlands