Insertion Reactions of Six-Membered Cyclopalladated N,N′,N″-Triarylguanidine, [Pd{κ2(C,N)-C6H3Me-3(NHC(NHAr)(═NAr))-2}(μ-Br)]2 (Ar = 2-MeC6H4) with PhC≡C—C(O)OR (R = Me and Et): A Gateway to Second Orthopalladation through Novel Rearrangements
Author:
Affiliation:
1. Department of Chemistry, University of Delhi, Delhi 110 007, India
2. Department of Inorganic and Physical Chemistry, Indian Institute of Science, Bangalore 560 012, Karnataka, India
Publisher
American Chemical Society (ACS)
Subject
Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/om4010719
Reference87 articles.
1. Espinet, P.; Albéniz, A. C.InFundamentals of Molecular Catalysis;Kurosawa, H., Yamamoto, A., Eds.Elsevier:New York, 2003; Vol.3, p293.
2. Hartwig, J. F.Organotransition Metal Chemistry: From Bonding to Catalysis;University Science Books:New York, 2010; Chapter 9, p349.
3. Cyclopalladated Complexes in Organic Synthesis
4. Reactions of cyclopalladated compounds and alkynes: New pathways for organic synthesis?
5. Selected applications to organic synthesis of intramolecular C-H activation reactions by transition metals
Cited by 10 articles. 订阅此论文施引文献 订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献
1. Guanidine-centred reactivity of CNN Pd(ii) pincer complexes including carboxylate-assisted N–H activation and –CH2– → –C(O)– oxygenation;New Journal of Chemistry;2024
2. A one-pot process for synthesis of eight-membered cyclopalladated amidines via cascade C H activation and insertion;Journal of Organometallic Chemistry;2020-10
3. Syntheses and structural aspects of six-membered palladacyclic complexes derived fromN,N′,N′′-triarylguanidines with N- or S-thiocyanate ligands;New Journal of Chemistry;2019
4. Six-membered cyclopalladated N,N′,N″-triarylguanidines, [{κ2(C,N)Pd}2(μ-OAc)(μ-Pz)], [κ2(C,N)Pd(μ-Pz)]2 and a novel [AgNO3⊂{{κ2(C,N)Pd}2(μ-NO3)(μ-Pz)}]: Syntheses, reactivity studies, structural aspects, and solution behavior;Polyhedron;2016-10
5. Direct Observation of C–H Cyclopalladation at Tertiary Positions Enabled by an Exo-Directing Group;Organometallics;2016-04-13
1.学者识别学者识别
2.学术分析学术分析
3.人才评估人才评估
"同舟云学术"是以全球学者为主线，采集、加工和组织学术论文而形成的新型学术文献查询和分析系统，可以对全球学者进行文献检索和人才价值评估。用户可以通过关注某些学科领域的顶尖人物而持续追踪该领域的学科进展和研究前沿。经过近期的数据扩容，当前同舟云学术共收录了国内外主流学术期刊6万余种，收集的期刊论文及会议论文总量共计约1.5亿篇，并以每天添加12000余篇中外论文的速度递增。我们也可以为用户提供个性化、定制化的学者数据。欢迎来电咨询！咨询电话：010-8811{复制后删除}0370
www.globalauthorid.com
TOP
Copyright © 2019-2024 北京同舟云网络信息技术有限公司 京公网安备11010802033243号 京ICP备18003416号-3