Experimental Evidence for a Temperature Dependent Transition between Normal and Inverse Equilibrium Isotope Effects for Oxidative Addition of H2 to Ir(PMe2Ph)2(CO)Cl-Reference-Cited by-同舟云学术

Experimental Evidence for a Temperature Dependent Transition between Normal and Inverse Equilibrium Isotope Effects for Oxidative Addition of H2 to Ir(PMe2Ph)2(CO)Cl

Published:2003-10-01 Issue:43 Volume:125 Page:13219-13224
ISSN:0002-7863
Container-title:Journal of the American Chemical Society
language:en
Short-container-title:J. Am. Chem. Soc.

Author:

Janak Kevin E.¹,Parkin Gerard¹

Affiliation:

1. Contribution from the Department of Chemistry, Columbia University, New York, New York 10027

Publisher

American Chemical Society (ACS)

Subject

Colloid and Surface Chemistry,Biochemistry,General Chemistry,Catalysis

Link

https://pubs.acs.org/doi/pdf/10.1021/ja0362611

Reference41 articles.

1. Generation of enantiopure trans-.DELTA.9,10-tricyclo[9.3.1.03,8]pentadecene diastereomers from a single precursor. Control of stereochemistry by means of rotationally restrictive nonbonded interactions

2. Mechanistic and Theoretical Analysis of the Oxidative Addition of H2 to Six-Coordinate Molybdenum and Tungsten Complexes M(PMe3)4X2 (M = Mo, W; X = F, Cl, Br, I): An Inverse Equilibrium Isotope Effect and an Unprecedented Halide Dependence

3. Theoretical evaluation of experimentally observed isotope effects

4. Theoretical study of primary and secondary deuterium equilibrium isotope effects for hydrogen and methane addition to iridium complex trans-Ir(PR3)2(CO)X

Cited by 36 articles. 订阅此论文施引文献订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献

1. Kinetic Isotope Effects and the Mechanism of CO₂ Insertion into the Metal-Hydride Bond of fac-(bpy)Re(CO)₃H;Inorganic Chemistry;2024-06-20

2. Equilibrium and kinetic isotope effects in heterogeneous catalysis: A density functional theory perspective;Catalysis Communications;2023-04

3. C–H Bond Activation Facilitated by Bis(phosphinoamide) Heterobimetallic Zr/Co Complexes;Organometallics;2021-10-20

4. Iridium-catalysed branched-selective hydroacylation of 1,3-dienes with salicylaldehydes;Chemical Communications;2021

5. Accelerating equilibrium isotope effect calculations. II. Stochastic implementation of direct estimators;The Journal of Chemical Physics;2019-10-07