Medium Effects on the Rates of Stereomutation of a Pair of Diastereomeric Cyclopropanones. Ground State Stabilization in Nucleophilic Solvents Induces Deviation from Solvent Polarity Controlled Behavior
Author:
Affiliation:
1. Contribution from the Department of Chemistry, Yale University, New Haven, Connecticut 06520
Publisher
American Chemical Society (ACS)
Subject
Colloid and Surface Chemistry,Biochemistry,General Chemistry,Catalysis
Link
https://pubs.acs.org/doi/pdf/10.1021/ja960481f
Reference63 articles.
1. Thermal interconversion of a pair of diastereomeric cyclopropanones. An upper limit for a cyclopropanone-oxyallyl energy separation
2. Stereochemistry of a Cyclopropanone by Crystal Structure Analysis. The Exo Configuration of the Diels-Alder Adduct of Cyclopropenone and 1,3-Diphenylisobenzofuran Appears To Be Stabilized Relative to the Endo by an Attractive Ether-Carbonyl Interaction
3. Solvent Effects on the Ring Opening of Cyclopropanones to Oxyallyls: A Combined ab Initio and Monte Carlo Study
4. Ab initio MCSCF and CI calculations of the singlet-triplet energy differences in oxyallyl and in dimethyloxyallyl
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