Development of a Rhodium Carbenoid-Initiated Claisen Rearrangement for the Enantioselective Synthesis of α-Hydroxy Carbonyl Compounds
Author:
Affiliation:
1. Sterling Chemistry Laboratory, Department of Chemistry Yale University, New Haven, Connecticut 06520-8107
Publisher
American Chemical Society (ACS)
Subject
Colloid and Surface Chemistry,Biochemistry,General Chemistry,Catalysis
Link
https://pubs.acs.org/doi/pdf/10.1021/ja983294l
Reference8 articles.
1. Synthetic applications of the O-H insertion reactions of carbenes and carbenoids derived from diazocarbonyl and related diazo compounds
2. C2-Symmetric Copper(II) Complexes as Chiral Lewis Acids. Catalytic Enantioselective Aldol Additions of Enolsilanes to Pyruvate Esters
3. The anionic oxy-claisen rearrangement of enolates of .alpha.-allyloxy ketones. A remarkable rate accelerating effect exhibited by the nature of the counterion
4. The thermal, aliphatic Claisen rearrangement
5. Total Synthesis of (+)- and (-)-K252a
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