Generation of Intramolecular Sulfur- or Selenium-Coordinated Silylenes by the Thermolysis of Pentacoordinate Disilanes Bearing an 8-Thio- or 8-Seleno-1-naphthyl Group and a Methoxy Group on the Same Silicon Atom-Reference-Cited by-同舟云学术

Generation of Intramolecular Sulfur- or Selenium-Coordinated Silylenes by the Thermolysis of Pentacoordinate Disilanes Bearing an 8-Thio- or 8-Seleno-1-naphthyl Group and a Methoxy Group on the Same Silicon Atom

Published:2003-07-10 Issue:16 Volume:22 Page:3299-3303
ISSN:0276-7333
Container-title:Organometallics
language:en
Short-container-title:Organometallics

Author:

Saeki Tomoyuki¹,Toshimitsu Akio¹,Tamao Kohei¹

Affiliation:

1. Institute for Chemical Research, Kyoto University, Uji, Kyoto 611-0011, Japan

Publisher

American Chemical Society (ACS)

Subject

Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry

Link

https://pubs.acs.org/doi/pdf/10.1021/om030190x

Reference18 articles.

1. Remarkably Facile Thermal Generation of Silylene from a Pentacoordinate Alkoxydisilane and Its Trapping as a Pentacoordinate 1,2-Disilacyclobut-3-ene

2. Trimerization of a Divalent Silicon Species Bearing the 8-Dimethylamino-1-naphthyl Group Accompanied by the Migration of Methyl and Dimethylamino Groups

3. Nucleophilic Addition of a Divalent Silicon Species Bearing the 8-Dimethylamino-1-naphthyl Group to Diphenylacetylenes to Form the 1-Amino-1-silaphenalene Skeleton

4. Enhanced nucleophilicity of ambiphilic silylene and silylenoid bearing 8-(dimethylamino)-1-naphthyl group

5. Phosphonium Sila-ylide: Reaction Pathway Different from Ammonium Sila-ylide but Similar to Phosphonium Ylide

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