Room-Temperature Energy-Sampling Kβ X-ray Emission Spectroscopy of the Mn4Ca Complex of Photosynthesis Reveals Three Manganese-Centered Oxidation Steps and Suggests a Coordination Change Prior to O2 Formation
Author:
Affiliation:
1. Freie Universität Berlin, Department of Physics, 14195 Berlin, Germany
2. Uppsala University, Department of Chemistry, Ångström Laboratory, 75120 Uppsala, Sweden
Funder
Bundesministerium für Bildung und Forschung
Energimyndigheten
Deutsche Forschungsgemeinschaft
Knut och Alice Wallenbergs Stiftelse
Publisher
American Chemical Society (ACS)
Subject
Biochemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/acs.biochem.6b00491
Reference141 articles.
1. Photosystem II: the engine of life
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4. Photosystem II: The machinery of photosynthetic water splitting
5. Mn4Ca Cluster in Photosynthesis: Where and How Water is Oxidized to Dioxygen
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