Room-Temperature Energy-Sampling Kβ X-ray Emission Spectroscopy of the Mn4Ca Complex of Photosynthesis Reveals Three Manganese-Centered Oxidation Steps and Suggests a Coordination Change Prior to O2 Formation

Author:

Zaharieva Ivelina1,Chernev Petko1,Berggren Gustav2,Anderlund Magnus2,Styring Stenbjörn2,Dau Holger1,Haumann Michael1

Affiliation:

1. Freie Universität Berlin, Department of Physics, 14195 Berlin, Germany

2. Uppsala University, Department of Chemistry, Ångström Laboratory, 75120 Uppsala, Sweden

Funder

Bundesministerium für Bildung und Forschung

Energimyndigheten

Deutsche Forschungsgemeinschaft

Knut och Alice Wallenbergs Stiftelse

Publisher

American Chemical Society (ACS)

Subject

Biochemistry

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