Enzymatic Transformation and Liquid-Chromatographic Separation as Methods for the Preparation of the (R)- and (S)-Enantiomers of the Centrochiral Hydridogermanes p-XC6H4(H)Ge(CH2OAc)CH2OH (X = H, F)

Author:

Tacke Reinhold1,Kosub Ulrike1,Wagner Stephan A.1,Bertermann Rüdiger1,Schwarz Sigrid1,Merget Stefan1,Günther Kurt1

Affiliation:

1. Institut für Anorganische Chemie, Universität Würzburg, Am Hubland, D-97074 Würzburg, Germany, and Zentrale Forschungseinrichtungen der Degussa AG, Rodenbacher Chaussee 4, D-63457 Hanau-Wolfgang, Germany

Publisher

American Chemical Society (ACS)

Subject

Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry

Reference11 articles.

1. Recent publications dealing with optically active silicon compounds of the formula type R1R2SiR3R4:  (a) Sheldrick, W. S.; Linoh, H.; Tacke, R.; Lambrecht, G.; Moser, U.; Mutschler, E.J. Chem. Soc., Dalton Trans.1985, 1743−1746. (b) Terunuma, D.; Kato, M.; Kamai, M.; Uchida, H.; Ueno, S.; Nohira, H.Bull. Chem. Soc. Jpn.1986,59, 3581−3587. (c) Tacke, R.; Becker, B.Main Group Met. Chem.1987,10, 169−197. (d) Tacke, R.; Linoh, H.; Ernst, L.; Moser, U.; Mutschler, E.; Sarge, S.; Cammenga, H. K.; Lambrecht, G.Chem. Ber.1987,120, 1229−1237. (e) Larson, G. L.; Prieto, J. A.; Ortiz, E.Tetrahedron1988,44, 3781−3790. (f) Syldatk, C.; Stoffregen, A.; Brans, A.; Fritsche, K.; Andree, H.; Wagner, F.; Hengelsberg, H.; Tafel, A.; Wuttke, F.; Zilch, H.; Tacke, R. InEnzyme Engineering 9; Blanch, H. W., Klibanov, A. M., Eds.Ann. N.Y. Acad. Sci.; The New York Academy of Sciences:  New York, 1988; Vol. 542, pp 330−338. (g) Terunuma, D.; Yamamoto, N.; Kizaki, H.; Nohira, H.Nippon Kagaku Kaishi1990,32, 451−456. (h) Djerourou, A.H.; Blanco, L.Tetrahedron Lett.1991,32, 6325−6326. (i) Tacke, R.; Brakmann, S.; Wuttke, F.; Fooladi, J.; Syldatk, C.; Schomburg, D.J.Organomet. Chem.1991,403, 29−41. (j) Tacke, R.; Brakmann, S.; Kropfgans, M.; Strohmann, C.; Wuttke, F.; Lambrecht, G.; Mutschler, E.; Proksch, P.; Schiebel, H.M.; Witte, L. InFrontiers of OrganosiliconChemistry; Bassindale, A. R., Gaspar, P. P., Eds.; The Royal Society of Chemistry:  Cambridge, U.K., 1991; pp 218−228. (k) Tacke, R.; Wuttke, F.; Henke, H.J. Organomet. Chem.1992,424, 273−286. (l) Yamamoto, K.; Kawanami, Y.; Miyazawa, M.J. Chem. Soc., Chem. Commun.1993, 436−437. (m) Ohta, T.; Ito, M.; Tsuneto, A.; Takaya, H.J. Chem. Soc., Chem.Commun.1994, 2525−2526. (n) Fukui, T.; Kawamoto, T.; Tanaka, A.Tetrahedron Asymmetry1994,5, 73−82. (o) Tacke, R.; Reichel, D.; Günther, K.; Merget, S.Z. Naturforsch., B1995,50, 568−572. (p) Tacke, R.; Reichel, D.; Kropfgans, M.; Jones, P. G.; Mutschler, E.; Gross, J.; Hou, X.; Waelbroeck, M.; Lambrecht, G.Organometallics1995,14, 251−262. (q) Huber, P.; Bratovanov, S.; Bienz, S.; Syldatk, C.; Pietzsch, M.TetrahedronAsymmetry1996,7, 69−78. (r) Reichel, D.; Tacke, R.; Jones, P. G.; Lambrecht, G.; Gross, J.; Mutschler, E.; Waelbroeck, M. InOrganosiliconChemistry II-From Molecules to Materials; Auner, N., Weis, J., Eds.; VCH:  Weinheim, Germany, 1996; pp 231−236. (s) Wagner, S. A.; Brakmann, S.; Tacke, R. InOrganosilicon Chemistry II-From Molecules to Materials; Auner, N., Weis, J., Eds.; VCH:  Weinheim, Germany, 1996; pp 237−242. (t) Kobayashi, K.; Kato, T.; Unno, M.; Masuda, S.Bull. Chem. Soc. Jpn.1997,70, 1393−1401.

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