A General Solution for Unstable Boronic Acids: Slow-Release Cross-Coupling from Air-Stable MIDA Boronates
Author:
Affiliation:
1. Roger Adams Lab, Department of Chemistry, University of Illinois at Urbana−Champaign, Urbana, Illinois 61801
Publisher
American Chemical Society (ACS)
Subject
Colloid and Surface Chemistry,Biochemistry,General Chemistry,Catalysis
Link
https://pubs.acs.org/doi/pdf/10.1021/ja901416p
Reference65 articles.
1. Boronic Acids
2. In a recent systematic study, even the powerful diaryldialkylphosphine ligands developed by Buchwald and coworkers failed to promote efficient couplings of 2-substituted furan, thiophene, and pyrrole boronic acids with unactivated aryl chlorides:
3. Highly Efficient Monophosphine-Based Catalyst for the Palladium-Catalyzed Suzuki−Miyaura Reaction of Heteroaryl Halides and Heteroaryl Boronic Acids and Esters
4. For some examples of coupling of 2-heterocyclic boronic acids with activated aryl and acid chlorides, see:
5. aref2.
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