Weakening C−O Bonds: Ti(III), a New Reagent for Alcohol Deoxygenation and Carbonyl Coupling Olefination-Reference-Cited by-同舟云学术

Weakening C−O Bonds: Ti(III), a New Reagent for Alcohol Deoxygenation and Carbonyl Coupling Olefination

Published:2009-12-11 Issue:1 Volume:132 Page:254-259
ISSN:0002-7863
Container-title:Journal of the American Chemical Society
language:en
Short-container-title:J. Am. Chem. Soc.

Author:

Diéguez Horacio R.¹,López Armando¹,Domingo Victoriano¹,Arteaga Jesús F.¹,Dobado José A.¹,Herrador M. Mar¹,Quílez del Moral José F.¹,Barrero Alejandro F.¹

Affiliation:

1. Department of Organic Chemistry, Institute of Biotechnology, University of Granada, Avda. Fuentenueva, 18071 Granada, Spain, and Department of Chemical Engineering, Physical Chemistry and Organic Chemistry, Faculty of Experimental Sciences, University of Huelva, Campus el Carmen, 21071 Huelva, Spain

Publisher

American Chemical Society (ACS)

Subject

Colloid and Surface Chemistry,Biochemistry,General Chemistry,Catalysis

Link

https://pubs.acs.org/doi/pdf/10.1021/ja906083c

Reference52 articles.

1. The single electron transfer bis(cyclopentadienyl)-titanium(III)chloride, Nugent’s reagent, can be generated in situ by stirring commercial Cp2TiCl2with dust Mn or Zn. For pioneering reports on the use of this reagent, see:

2. Selective Generation of Free Radicals from Epoxides Using a Transition-Metal Radical. A Powerful New Tool for Organic Synthesis

3. Reagent-Controlled Transition-Metal-Catalyzed Radical Reactions

4. cGansäuer, A. and Pierobon, M.InRadicals in Organic Synthesis;Renaud, P. and Sibi, M. P., Eds.Wiley-VCH:Weinheim, Germany, 2001; Vol.2, pp207−220.

5. Strained Heterocycles in Radical Chemistry

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