Insertion of Acetonitrile into the Zr−P Bond of [Cp°2ZrCl(PHCy)] (Cy = Cyclohexyl, Cp° = η5-C5EtMe4) Followed by PHCy Elimination To Give [Cp°2(Cl)Zr(μ-NCMe−CMeN)Zr(Cl)Cp°2]-Reference-Cited by-同舟云学术

Insertion of Acetonitrile into the Zr−P Bond of [Cp°2ZrCl(PHCy)] (Cy = Cyclohexyl, Cp° = η5-C5EtMe4) Followed by PHCy Elimination To Give [Cp°2(Cl)Zr(μ-NCMe−CMeN)Zr(Cl)Cp°2]

Published:1999-07-01 Issue:15 Volume:18 Page:2838-2842
ISSN:0276-7333
Container-title:Organometallics
language:en
Short-container-title:Organometallics

Author:

Segerer Ulrike¹,Blaurock Steffen¹,Sieler Joachim¹,Hey-Hawkins Evamarie¹

Affiliation:

1. Institut für Anorganische Chemie der Universität, Talstrasse 35, D-04103 Leipzig, Germany

Publisher

American Chemical Society (ACS)

Subject

Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry

Link

https://pubs.acs.org/doi/pdf/10.1021/om9901271

Reference27 articles.

1. Alkali-Phosphorverbindungen und ihr reaktives Verhalten XLIV. Cyclopentadienyl-Metallphosphide des Titan(III) und Zirkon(III)

2. Synthesis and molecular structures of homoleptic dicyclohexylphosphide complexes of the early transition metals

3. Bis(cyclopentadienyl)zirconium(IV) or hafnium-(IV) Compounds with Si-, Ge-, Sn-, N-, P-, As-, Sb-, O-, S-, Se-, Te-, or Transition Metal-Centered Anionic Ligands

4. Bis(trimethylsilyl)phosphinodithioformates, the phosphorus analogues of dithiocarbamates; X-ray structure of [Zr(cp)2(Cl)(η2-S2CPR2)] and its thermolysis product [{Zr(cp)2(µ-S)}2](cp =η-C5H5, R = SiMe3)

5. Formation of novel P-functionalized ligands by insertion reactions into the ZrP bond of Cp2°ZrCl(PHCy) (Cp°η5-C5EtMe4 Cy = cyclohexyl)

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