Mechanism of α-Ketol-Type Rearrangement of Benzoin Derivatives under Basic Conditions
Author:
Affiliation:
1. Department of Chemistry and the Research Center for Smart Molecules, Rikkyo University, Nishi-Ikebukuro, Toshima-ku, 171-8501 Tokyo, Japan
Publisher
American Chemical Society (ACS)
Subject
Organic Chemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/jo401156h
Reference22 articles.
1. Reduction of Alkynyl α-Hydroxy Esters: Stereoselective α-Ketol Rearrangement
2. Acyloin rearrangement of α-hydroxy acetals: Application to the methyl l-mycaroside synthesis
3. Base-catalysed acyloin rearrangements: the first synthesis of 4-arylflavan-3-ones via chalcone epoxides
4. Synthesis of some 4-hydroxy-2-pyrrolin-5-one derivatives via acyloin rearrangement
5. Synthesis of bridgehead hydroxyl-substituted benzobicyclo[3.2.1]octenes and -octadienes via an acyloin rearrangement in the benzobicyclo[2.2.2]octene ring system
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1. Double Proton Transfer during a Novel Tertiary α-Ketol Rearrangement in Ketol-Acid Reductoisomerase: A Water-Mediated, Metal-Catalyzed, Base-Induced Mechanism;The Journal of Physical Chemistry B;2021-10-07
2. Base-Promoted Three-Component Cascade Reaction of α-Hydroxy Ketones, Malonodinitrile, and Alcohols: Direct Access to Tetrasubstituted NH-Pyrroles;The Journal of Organic Chemistry;2021-07-06
3. Intramolecular Benzoin Reaction Catalyzed by Benzaldehyde Lyase from Pseudomonas Fluorescens Biovar I;Angewandte Chemie International Edition;2017-04-07
4. Intramolecular Benzoin Reaction Catalyzed by Benzaldehyde Lyase from Pseudomonas Fluorescens Biovar I;Angewandte Chemie;2017-04-07
5. Molecular Rearrangements;Organic Reaction Mechanisms · 2013;2016-10-07
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