A Simple Method To Determine Kinetic Deuterium Isotope Effects Provides Evidence that Proton Transfer to Carbon Proceeds over and Not through the Reaction Barrier

Author:

Tsang Wing-Yin1,Richard John P.1

Affiliation:

1. Department of Chemistry, University at Buffalo, Buffalo, New York 14260

Publisher

American Chemical Society (ACS)

Subject

Colloid and Surface Chemistry,Biochemistry,General Chemistry,Catalysis

Reference14 articles.

1. Kiefer, P. M.; Hynes, J. T. InHydrogen Transfer Reactions;Hynes, J. T., Klinman, J. P., Limbach, H.H., Schowen, R. L., Eds.; Wiley-VCH:  Weinheim, Germany, 2007; Vol. 1, pp 303−348. Williams, I. H. InHydrogen Transfer Reactions;Hynes, J. T., Klinman, J. P., Limbach, H.H., Schowen, R. L., Eds.; Wiley-VCH:  Weinheim, Germany, 2007; Vol. 2, pp 583−602.

2. Truhlar, D. C.; Garrett, B. C. InIsotope Effects in Chemistry and Biology; Kohen, A., Limbach, H.H., Eds.; Taylor & Francis:  New York, 2006; pp 579−620.

3. Reactivity of cyclic and acyclic olefinic hydrocarbons in acid-catalyzed hydration

4. The Magnitude of the Primary Kinetic Isotope Effect for Compounds of Hydrogen and Deuterium.

5. Bell, R. P.The Proton in Chemistry, 2nd ed.; Cornell University Press:  Ithaca, NY, 1973; pp 250−296.

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