Solution Interaction of Potassium and Calcium Bis(trimethylsilyl)amides; Preparation of Ca[N(SiMe3)2]2 from Dibenzylcalcium
Author:
Affiliation:
1. The Dow Chemical Company, Freeport, Texas 77541, and Department of Chemistry, Vanderbilt University, Nashville, Tennessee 37235
Publisher
American Chemical Society (ACS)
Subject
Inorganic Chemistry,Physical and Theoretical Chemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/ic8012766
Reference37 articles.
1. Synthesis, properties, and reactivity of alkaline earth metal bis[bis(trialkylsilyl)amides]
2. bHanusa, T. P.InComprehensive Coordination Chemistry,2nd ed.McCleverty, J. A. and Meyer, T. B., Eds.Elsevier: Oxford, 2004; Vol.3, p1−92;
3. Syntheses, Structures, and Reactivity of Barium Carbene Complexes with Chelating Bis-iminophosphorano Arms
4. Structural Trends in Alkaline Earth and Rare Earth Metal 3,5‐Diisopropylpyrazolates
5. The synthesis and structure of the alkaline earth metal organic compounds [M(OAr)2(thf)n][M = Ca, n= 3 (1) or 0; M = Ba, n= 4] and [{Ca(NR2)(µNR2)(thf)}2], and the X-ray structure of (1)(Ar = C6H2But2-2,6-Me-4; R = SiMe3; thf - OC4H8)
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