Highly Electrophilic, 16-Electron [Ru(P(OMe)(OH)2)(dppe)2]2+ Complex Turns H2(g) into a Strong Acid and Splits a Si−H Bond Heterolytically. Synthesis and Structure of the Novel Phosphorous Acid Complex [Ru(P(OH)3)(dppe)2]2+-Reference-Cited by-同舟云学术

Highly Electrophilic, 16-Electron [Ru(P(OMe)(OH)2)(dppe)2]2+ Complex Turns H2(g) into a Strong Acid and Splits a Si−H Bond Heterolytically. Synthesis and Structure of the Novel Phosphorous Acid Complex [Ru(P(OH)3)(dppe)2]2+

Published:2005-05-17 Issue:12 Volume:44 Page:4145-4147
ISSN:0020-1669
Container-title:Inorganic Chemistry
language:en
Short-container-title:Inorg. Chem.

Author:

Nagaraja C. M.¹,Nethaji Munirathinam¹,Jagirdar Balaji R.¹

Affiliation:

1. Department of Inorganic & Physical Chemistry, Indian Institute of Science, Bangalore 560 012, India

Publisher

American Chemical Society (ACS)

Subject

Inorganic Chemistry,Physical and Theoretical Chemistry

Link

https://pubs.acs.org/doi/pdf/10.1021/ic050026x

Reference47 articles.

1. HETEROLYTIC SPLITTING OF HH, SiH, AND OTHER σ BONDS ON ELECTROPHILIC METAL CENTERS

2. Reactions of transition metal dihydrogen complexes

3. Novel double dealkylation of trialkylphosphite in the presence of an acid: synthesis and characterization of a 16-electron ruthenium complex bearing P(OH) 2 (OMe) ligand

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