Mechanistic Aspects of Hydrosilane/Potassium tert-Butoxide (HSiR3/KOtBu)-Mediated Reactions
Author:
Affiliation:
1. Griffith Institute for Drug Discovery, Griffith University, Nathan, QLD 4111, Australia
2. School of Chemistry and Molecular Biosciences, The University of Queensland, Brisbane, QLD 4072, Australia
Funder
Australian Research Council
University of Queensland
Publisher
American Chemical Society (ACS)
Subject
General Chemical Engineering,General Chemistry
Link
http://pubs.acs.org/doi/pdf/10.1021/acsomega.0c00366
Reference17 articles.
1. Silylation of C–H bonds in aromatic heterocycles by an Earth-abundant metal catalyst
2. bToutov, A.; Liu, W.; Grubbs, R. H.; Stoltz, B. M.; Betz, K.; Schuman, D. P. Patent Appl. WO/2016/100606, 2016.
3. Potassium tert-Butoxide-Catalyzed Dehydrogenative C–H Silylation of Heteroaromatics: A Combined Experimental and Computational Mechanistic Study
4. Ionic and Neutral Mechanisms for C–H Bond Silylation of Aromatic Heterocycles Catalyzed by Potassium tert-Butoxide
5. Synthesis and X-ray crystal structures of the one-dimensional ribbon chains [MOBut·ButOH]∞ and the cubane species [MOBut]4 (M = K and Rb)
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