Effect of Propargylic Substituents on Enantioselectivity and Reactivity in Ruthenium-Catalyzed Propargylic Substitution Reactions: A DFT Study
Author:
Affiliation:
1. Faculty of Pharmaceutical Sciences, Toho University, Funabashi, Chiba 274-8510, Japan
2. Department of Applied Chemistry, School of Engineering, The University of Tokyo, Tokyo 113-8656, Japan
Funder
Japan Society for the Promotion of Science
Publisher
American Chemical Society (ACS)
Subject
General Chemical Engineering,General Chemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/acsomega.2c04645
Reference71 articles.
1. Development of Asymmetric Propargylic Substitution Reactions Using Transition Metal Catalysts
2. Transition‐Metal‐Catalyzed Propargylic Substitution of Propargylic Alcohol Derivatives Bearing an Internal Alkyne Group
3. Recent advances in copper-catalyzed propargylic substitution
4. Transition-Metal-Catalyzed Enantioselective Propargylic Substitution Reactions of Propargylic Alcohol Derivatives with Nucleophiles
5. Catalytic Asymmetric Propargylation
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1. Enantioselective propargylic amination and related tandem sequences to α-tertiary ethynylamines and azacycles;Nature Chemistry;2024-03-19
2. Asymmetric Propargylic C−C Bond Formation Using Metal–Allenylidene Species;European Journal of Organic Chemistry;2023-11-22
3. Interplay of diruthenium catalyst in controlling enantioselective propargylic substitution reactions with visible light-generated alkyl radicals;Nature Communications;2023-02-23
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