Diels−Alder Reactions of Perfluorobicyclo[2.2.0]hex-1(4)-ene with Aromatics

Author:

He Yigang1,Junk Christopher P.1,Lemal David M.1

Affiliation:

1. Department of Chemistry, Dartmouth College, Hanover, New Hampshire 03755

Publisher

American Chemical Society (ACS)

Subject

Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

Reference13 articles.

1. Walter H. Stockmayer Fellow, 1998−2000.

2. Octafluorobicyclo[2.2.0]hex-1(4)-ene:  A Greatly Strained Alkene with Novel Reactivity

3. Bicyclo[2.2.0]hex-1(4)-ene

4. Relative to the respective starting materials, the radical resulting from hydrogen atom attack at the α position of naphthalene lies 14.3 kcal/mol above that from attack at the β position of styrene at the HF/6-31G*//3-21G level of theory (0 K, uncorrected for ΔEzpt); for the corresponding cations, the difference is 10.6 kcal/mol. (Spartan:  Hehre, W.; Wavefunction, Inc.  188401 Von Karman, Suite 370, Irvine, CA 92717.)

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