Alkylidene and Metalacyclic Complexes of Tungsten that Contain a Chiral Biphenoxide Ligand. Synthesis, Asymmetric Ring-Closing Metathesis, and Mechanistic Investigations
Author:
Affiliation:
1. Contribution from the Department of Chemistry, Massachusetts Institute of Technology, Cambridge, Massachusetts 02139, and Department of Chemistry, Merkert Chemistry Center, Boston College, Chestnut Hill, Massachusetts 02467
Publisher
American Chemical Society (ACS)
Subject
Colloid and Surface Chemistry,Biochemistry,General Chemistry,Catalysis
Link
https://pubs.acs.org/doi/pdf/10.1021/ja0210603
Reference102 articles.
1. (Diphenylcarbene)pentacarbonyltungsten(0)
2. Reactions of (diphenylcarbene)pentacarbonyltungsten(0) with alkenes. Role of metal-carbene complexes in cyclopropanation and olefin metathesis reactions
3. Reactions of (CO)5WC(Tol)2 with alkenes. A Model for structural selectivity in the olefin metathesis reaction
4. Synthesis and crystal structure of diphenylcarbene(pentacarbonyl)tungsten(0)
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