A Study of the OH--Induced β-Elimination Reactions of 2-(4-Chloroethyl)pyridine, 2-(2-Chloroethyl)pyridine, 1-Methyl-2-(4-chloroethyl)pyridinium Iodide and 1-Methyl-2-(2-chloroethyl)pyridinium Iodide in Acetonitrile/Water-Reference-Cited by-同舟云学术

A Study of the OH--Induced β-Elimination Reactions of 2-(4-Chloroethyl)pyridine, 2-(2-Chloroethyl)pyridine, 1-Methyl-2-(4-chloroethyl)pyridinium Iodide and 1-Methyl-2-(2-chloroethyl)pyridinium Iodide in Acetonitrile/Water

Published:2004-07-29 Issue:18 Volume:69 Page:6121-6123
ISSN:0022-3263
Container-title:The Journal of Organic Chemistry
language:en
Short-container-title:J. Org. Chem.

Author:

Alunni Sergio¹,Del Giacco Tiziana¹,De Maria Paolo¹,Fontana Antonella¹,Gasbarri Carla¹,Ottavi Laura¹

Affiliation:

1. Dipartimento di Chimica, Università degli Studi Perugia, Via Elce di Sotto 8, 06123 Perugia Italy, and Dipartimento di Scienze del Farmaco, Università “G. D'Annunzio”, Via dei Vestini 31, 66013 Chieti, Italy alunnis@unipg.it

Publisher

American Chemical Society (ACS)

Subject

Organic Chemistry

Link

https://pubs.acs.org/doi/pdf/10.1021/jo040117w

Reference14 articles.

1. Mechanism and proton activating factors in base-induced β-elimination reactions of N-[2-(4-pyridyl)ethyl]quinuclidinium and N-[2-(2-pyridyl)ethyl]quinuclidinium salts †

2. Mechanism and proton activating factors in base-induced β-elimination reactions of 2-(2-chloroethyl)pyridine †

3. Catalysis of the β-Elimination of HF from Isomeric 2-Fluoroethylpyridines and 1-Methyl-2-fluoroethylpyridinium Salts. Proton-Activating Factors and Methyl-Activating Factors as a Mechanistic Test To Distinguish between Concerted E2 and E1cb Irreversible Mechanisms

4. Use of solvent isotope effect to identify an intermediate carbanion in the β-elimination reactions from N-[2-(4-pyridyl)ethyl]quinuclidinium and N-[2-(2-pyridyl)ethyl]quinuclidinium induced by acetohydroxamate/acetohydroxamic acid buffers

5. Proton activating factors in general acid and general base catalysis

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