Electron-Transfer Oxidation of Coenzyme B12 Model Compounds and Facile Cleavage of the Cobalt(IV)−Carbon Bond via Charge-Transfer Complexes with Bases. A Negative Temperature Dependence of the Rates
Author:
Affiliation:
1. Department of Material and Life Science, Graduate School of Engineering, Osaka University, SORST, Japan Science and Technology Agency, Suita, Osaka 565-0871, Japan
Publisher
American Chemical Society (ACS)
Subject
Physical and Theoretical Chemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/jp0453008
Reference98 articles.
1. Mechanism of cobalamin-dependent rearrangements
2. (c) Schneider, Z.; Stroinski, A.ComprehensiveB12; de Gruyter: Berlin, 1987.
3. Towards the unification of coenzyme B12-dependent diol dehydratase stereochemical and model studies: The bound radical mechanism
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