Molecular Structures and Excited States of CpM(CO)2 (Cp = η5-C5H5; M = Rh, Ir) and [Cl2Rh(CO)2]-. Theoretical Evidence for a Competitive Charge Transfer Mechanism-Reference-Cited by-同舟云学术

Molecular Structures and Excited States of CpM(CO)2 (Cp = η5-C5H5; M = Rh, Ir) and [Cl2Rh(CO)2]-. Theoretical Evidence for a Competitive Charge Transfer Mechanism

Published:2002-02-20 Issue:11 Volume:124 Page:2664-2671
ISSN:0002-7863
Container-title:Journal of the American Chemical Society
language:en
Short-container-title:J. Am. Chem. Soc.

Author:

Hu Zhenming¹,Boyd Russell J.¹,Nakatsuji Hiroshi¹

Affiliation:

1. Contribution from the Department of Chemistry, Dalhousie University, Halifax, Nova Scotia, Canada B3H 4J3, and Department of Synthetic Chemistry and Biological Chemistry, Graduate School of Engineering, Kyoto University, Sakyo-ku, Kyoto 606-8501, Japan

Publisher

American Chemical Society (ACS)

Subject

Colloid and Surface Chemistry,Biochemistry,General Chemistry,Catalysis

Link

https://pubs.acs.org/doi/pdf/10.1021/ja0108178

Reference52 articles.

1. Carbon-hydrogen activation in completely saturated hydrocarbons: direct observation of M + R-H .fwdarw. M(R)(H)

2. Activation of carbon-hydrogen bonds in saturated hydrocarbons on photolysis of (.eta.5-C5Me5)(PMe3)IrH2. Relative rates of reaction of the intermediate with different types of carbon-hydrogen bonds and functionalization of the metal-bound alkyl groups

3. Oxidative addition of the carbon-hydrogen bonds of neopentane and cyclohexane to a photochemically generated iridium(I) complex

4. Matrix photochemistry of (.eta.5-cyclopentadienyl)bis(ethene)rhodium and (.eta.5-cyclopentadienyl)(ethene)carbonylrhodium: a test-bed for intermediates in C-H activation

5. Photoactivation of methane by η5-cyclopentadienyl and substituted η5-cyclopentadienyl Group 8 metal dicarbonyl complexes, [M(η5-C5R5)(CO)2](M = Rh or Ir, R = H or Me), and dicarbonyl(η5-indenyl)iridium: a matrix isolation study

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