Facile Insertion of Terminal Acetylenes into the RuII−NR2 Bond of a 14-Valence-Electron Complex
Author:
Affiliation:
1. Department of Chemistry and Molecular Structure Center, Indiana University, Bloomington, Indiana 47405
Publisher
American Chemical Society (ACS)
Subject
Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/om049435b
Reference44 articles.
1. Four-Coordinate, Planar Ru(II). A Triplet State as a Response to a 14-Valence Electron Configuration
2. Synthesis and reactivity of ruthenium amide-phosphine complexes. Facile conversion of a ruthenium amide to a ruthenium amine via dihydrogen activation and orthometalation. X-ray structure of RuCl(C6H4PPh2)[NH(SiMe2CH2PPh2)2]
3. Synthesis and reactivity of the iridium vinylidene Ir:C:CH2[N(SiMe2CH2PPh2)2]. Formation of carbon-carbon bonds via migratory insertion of a vinylidene unit
4. Synthesis and reactivity of the coordinatively unsaturated methylene complex Ir:CH2[N(SiMe2CH2PPh2)2]
5. Reaction of the Coordinatively Unsaturated Methylene Complex Ir:CH2[N(SiMe2CH2PPh2)2] with Olefins: Stereoselective Formation of Allyl Hydride Derivatives
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