Reduction of [ML(alkyne)2(η-C5R‘5)]+ (M = Mo or W, L = MeCN or CO, R‘ = H or Me, C5R‘5 = C5HPh4): Characterization of Radical Intermediates in the Reductive Coupling of Coordinated Alkynes-Reference-Cited by-同舟云学术

Reduction of [ML(alkyne)2(η-C5R‘5)]+ (M = Mo or W, L = MeCN or CO, R‘ = H or Me, C5R‘5 = C5HPh4): Characterization of Radical Intermediates in the Reductive Coupling of Coordinated Alkynes

Published:1999-07-17 Issue:16 Volume:18 Page:3201-3207
ISSN:0276-7333
Container-title:Organometallics
language:en
Short-container-title:Organometallics

Author:

Connelly Neil G.¹,Geiger William E.¹,Lovelace Sherri R.¹,Metz Bernhard¹,Paget Timothy J.¹,Winter Rainer¹

Affiliation:

1. School of Chemistry, University of Bristol, Bristol BS8 1TS, U.K., and Department of Chemistry, University of Vermont, Burlington, Vermont 05405

Publisher

American Chemical Society (ACS)

Subject

Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry

Link

https://pubs.acs.org/doi/pdf/10.1021/om990089l

Reference24 articles.

1. Molybdenum-centred carboncarbon bond formation reactions

2. Reactions of co-ordinated ligands. Part 43. Alkyne linking reactions at dimetal centres. Synthesis and structures of [Mo2{µ-(σ,η3:η2:η3,σ-C8H4But4)}(η-C5H5)2], [Mo2{µ-(σ,η3:η3,σ-CHCHButC6H2But3)}(η-C5H5)2], and [FeMo(CO)2(C4Me2Ph2)(η-C5H5)2]

3. Reactions of co-ordinated ligands. Part 36. The synthesis, structure, and reactivity of the three-alkyne ‘fly-over’ complex [Mo2{µ-(σ,η3:η3,σ-C6Me6)}(η5-C9H7)2]; formation and structure of [Mo2{µ-(σ,η3:η3,σ-C6Me6)}(CO)2(η5-C9H7)2]

4. Linking of four acetylene molecules at a dimolybdenum center and the protonation of the resulting metallacyclononatetraene to form a cation containing a bridging MoHC system

5. Reactions of co-ordinated ligands. Part 31. The synthesis, structure, and protonation of the octamethyloctatrienediylidenedimolybdenum complex [Mo2(µ-C8Me8)(η-C5H5)2], evidence for three-centre carbon–hydrogen–molybdenum interactions

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1. Isolation of a bis(imino)pyridine molybdenum(i) iodide complex through controlled reduction and interconversion of its reaction products;Dalton Transactions;2016

2. Molybdenum Compounds without CO or Isonitrile Ligands;Comprehensive Organometallic Chemistry III;2007

3. Molybdenum Compounds with CO or Isocyanides;Comprehensive Organometallic Chemistry III;2007

4. Molybdenum and Tungsten η2-Alkyne-1-thio Complexes Acting as Sulfur Donors in Homoleptic Werner Type Complexes with Nickel(II) and Palladium(II);Inorganic Chemistry;2006-05-17

5. Structural consequences of the one-electron reduction of d4[Mo(CO)2(η-PhCCPh)Tp′]+and the electronic structure of the d5radicals [M(CO)L(η-MeCCMe)Tp′] {L = CO and P(OCH2)3CEt};Dalton Trans.;2006