Heteroatomic Deltahedral Clusters: Synthesis and Structures of closo-[Bi3Ni4(CO)6]3-, closo-[Bi4Ni4(CO)6]2-, the Open Cluster [Bi3Ni6(CO)9]3-, and the Intermetalloid closo-[Nix@{Bi6Ni6(CO)8}]4-
Author:
Affiliation:
1. Contribution from the Department of Chemistry and Biochemistry, University of Notre Dame, Notre Dame, Indiana 46556
Publisher
American Chemical Society (ACS)
Subject
Colloid and Surface Chemistry,Biochemistry,General Chemistry,Catalysis
Link
https://pubs.acs.org/doi/pdf/10.1021/ja071044b
Reference95 articles.
1. Chemistry of Deltahedral Zintl Ions
2. Oxidative Coupling of Deltahedral [Ge9]4- Zintl Ions
3. [Ge9Ge9Ge9]6-: A Linear Trimer of 27 Germanium Atoms
4. [Ge9Ge9Ge9Ge9]8-: A Linear Tetramer of Nine-Atom Germanium Clusters, a Nanorod
5. First Synthesis of Group-14 Polyanions by Extraction of a Binary Alloy with dmf and a Novel Conformation of the (Ge9−Ge9)6− Dimer: Crystal Structures of [K6(Ge9−Ge9)](dmf)12, [Rb6(Ge9−Ge9)](dmf)12 and [K2.5Cs3.5(Ge9−Ge9)](dmf)12.
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