Reversible Glutamate Coordination to High-Valent Nickel Protects the Active Site of a [NiFe] Hydrogenase from Oxygen

Author:

Kulka-Peschke Catharina J.1ORCID,Schulz Anne-Christine1,Lorent Christian1ORCID,Rippers Yvonne2,Wahlefeld Stefan1,Preissler Janina1,Schulz Claudia1,Wiemann Charlotte1,Bernitzky Cornelius C. M.2,Karafoulidi-Retsou Chara1,Wrathall Solomon L. D.3,Procacci Barbara3ORCID,Matsuura Hiroaki4,Greetham Gregory M.5,Teutloff Christian2ORCID,Lauterbach Lars6,Higuchi Yoshiki7,Ishii Masaharu8,Hunt Neil T.3ORCID,Lenz Oliver1ORCID,Zebger Ingo1ORCID,Horch Marius2ORCID

Affiliation:

1. Institut für Chemie, Sekr. PC14, Technische Universität Berlin, Straße des 17. Juni 135, D-10623 Berlin, Germany

2. Fachbereich Physik, Freie Universität Berlin, Arnimallee 14, D-14195 Berlin, Germany

3. Department of Chemistry & York Biomedical Research Institute, University of York, Heslington, York YO10 5DD, U.K.

4. Life Science Research Infrastructure Group, RIKEN/SPring-8 Center, 1-1-1 Kouto, Sayo-cho, Sayo-gun, Hyogo 679-5148, Japan

5. STFC Central Laser Facility, Research Complex at Harwell, Rutherford Appleton Laboratory, Harwell Science and Innovation Campus, Didcot, Oxford OX11 0QX, U.K.

6. Institute of Applied Microbiology, Synthetic Microbiology, RWTH Aachen University, Worringer Weg 1, D-52074 Aachen, Germany

7. Graduate School of Science, University of Hyogo, 3-2-1 Koto, Kamigori-cho, Ako-gun, Hyogo 678-1297, Japan

8. Graduate School of Agricultural and Life Sciences / Faculty of Agriculture, The University of Tokyo, 1-1-1, Yayoi, Bunkyo-ku, Tokyo 113-8657, Japan

Funder

Leverhulme Trust

Ministry of Education, Culture, Sports, Science and Technology

Science and Technology Facilities Council

Deutsche Forschungsgemeinschaft

Japan Society for the Promotion of Science

Einstein Stiftung Berlin

Horizon 2020 Framework Programme

Publisher

American Chemical Society (ACS)

Subject

Colloid and Surface Chemistry,Biochemistry,General Chemistry,Catalysis

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