Enzymatic Control over Reactive Intermediates Enables Direct Oxidation of Alkenes to Carbonyls by a P450 Iron-Oxo Species-Reference-Cited by-同舟云学术

Enzymatic Control over Reactive Intermediates Enables Direct Oxidation of Alkenes to Carbonyls by a P450 Iron-Oxo Species

Published:2022-08-23 Issue:35 Volume:144 Page:15954-15968
ISSN:0002-7863
Container-title:Journal of the American Chemical Society
language:en
Short-container-title:J. Am. Chem. Soc.

Author:

Soler Jordi¹^ORCID,Gergel Sebastian²,Klaus Cindy²^ORCID,Hammer Stephan C.²^ORCID,Garcia-Borràs Marc¹^ORCID

Affiliation:

1. Institut de Química Computacional i Catàlisi (IQCC) and Departament de Química, Universitat de Girona, Carrer Maria Aurèlia Capmany 69, Girona 17003, Catalonia, Spain

2. Chair of Organic Chemistry and Biocatalysis, Faculty of Chemistry, Bielefeld University, Universitätsstraße 25, 33615 Bielefeld, Germany

Funder

Ministerio de Ciencia e Innovaci?n

Deutsche Forschungsgemeinschaft

Ag?ncia de Gesti? d?Ajuts Universitaris i de Recerca

H2020 Marie Sklodowska-Curie Actions

Ministerio de Universidades

Publisher

American Chemical Society (ACS)

Subject

Colloid and Surface Chemistry,Biochemistry,General Chemistry,Catalysis

Link

https://pubs.acs.org/doi/pdf/10.1021/jacs.2c02567

Reference66 articles.

1. Palladium-Catalyzed anti-Markovnikov Oxidation of Terminal Alkenes

2. Practical and General Palladium-Catalyzed Synthesis of Ketones from Internal Olefins

3. Catalytic Selective Synthesis

4. Catalytic asymmetric epoxidations with chiral iron porphyrins

5. Multi-State Epoxidation of Ethene by Cytochrome P450: A Quantum Chemical Study

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