C−H Bonds Are Not Elongated by Coordination to Lanthanide Metals: Single-Crystal Neutron Diffraction Structures of (C5Me5)Y(OC6H3tBu2)CH(SiMe3)2 at 20 K and (C5Me5)La{CH(SiMe3)2}2 at 15 K-Reference-Cited by-同舟云学术

C−H Bonds Are Not Elongated by Coordination to Lanthanide Metals: Single-Crystal Neutron Diffraction Structures of (C5Me5)Y(OC6H3tBu2)CH(SiMe3)2 at 20 K and (C5Me5)La{CH(SiMe3)2}2 at 15 K

Published:1999-01-28 Issue:6 Volume:121 Page:1381-1382
ISSN:0002-7863
Container-title:Journal of the American Chemical Society
language:en
Short-container-title:J. Am. Chem. Soc.

Author:

Klooster Wim T.¹,Brammer Lee¹,Schaverien Colin. J.¹,Budzelaar Peter H. M.¹

Affiliation:

1. Chemistry Department, Brookhaven National Laboratory Upton, New York 11973-5000 Department of Chemistry, University of MissouriSt. Louis St. Louis, Missouri 63121-4499 Shell Research and Technology Centre Amsterdam Postbus 38000, 1030 BN Amsterdam, The Netherlands Department of Inorganic Chemistry, University of Nijmegen Toernooiveld 1, 6525 ED Nijmegen, The Netherlands

Publisher

American Chemical Society (ACS)

Subject

Colloid and Surface Chemistry,Biochemistry,General Chemistry,Catalysis

Link

https://pubs.acs.org/doi/pdf/10.1021/ja983068b

Reference14 articles.

1. Organometallic Chemistry of the Lanthanides

2. Highly reactive organolanthanides. Systematic routes to and olefin chemistry of early and late bis(pentamethylcyclopentadienyl) 4f hydrocarbyl and hydride complexes

3. Highly reactive organolanthanides. Synthesis, chemistry, and structures of 4f hydrocarbyls and hydrides with chelating bis(polymethylcyclopentadienyl) ligands

4. Mono(pentamethylcyclopentadienyl) complexes of cerium(III). Synthesis, molecular structure, thermal stability, and reactivity of (C5Me5)CeX2 (X = 2,6-di-tert-butylphenoxo, CH(SiMe3)2, and N(SiMe3)2) complexes

5. Synthesis of monomeric permethylyttrocene derivatives. The crystal structures of Cp2*YN(SiMe3)2 and Cp2*YCH(SiMe3)2

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