Mild Reduction Route to a Redox-Active Silicon Complex: Structure and Properties of (IP2–)2Si and (IP–)2Mg(THF) (IP = α-Iminopyridine)
Author:
Affiliation:
1. Department of Chemistry, University of California, Davis, California 95616, United States
Publisher
American Chemical Society (ACS)
Subject
Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/om300242q
Reference31 articles.
1. Neutral Bis(α-iminopyridine)metal Complexes of the First-Row Transition Ions (Cr, Mn, Fe, Co, Ni, Zn) and Their Monocationic Analogues: Mixed Valency Involving a Redox Noninnocent Ligand System
2. Sodium and Potassium Salts of Mono- and Dianionic α-Iminopyridines
3. An Electron-Transfer Series of High-Valent Chromium Complexes with Redox Non-Innocent, Non-Heme Ligands
4. Steric Manipulation of the Reductive Reactivity of Ytterbocenes toward 2-(((2,6-Diisopropylphenyl)imino)methyl)pyridine: Insertion of the NC Bond into the Yb−Indenyl Bond or Oxidative Cleavage of the η5 Yb−Cp (Cp = C13H9, Cp*) Bond
5. A Strategy for the Synthesis of Well-Defined Iron Catalysts and Application to Regioselective Diene Hydrosilylation
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