Decanuclear Manganese(III) Complexes with the [Mn10O8]14+ Core: Structural and Magnetochemical Characterization of [Mn10O8(O2CPh)6(chel)8] (chel = pic, dbm)
Author:
Affiliation:
1. Department of Chemistry and the Molecular Structure Center, Indiana University, Bloomington, Indiana 47405-4001, and the Department of Chemistry0358, University of California at San Diego, La Jolla, California 92093-0358
Publisher
American Chemical Society (ACS)
Subject
Inorganic Chemistry,Physical and Theoretical Chemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/ic9607548
Reference39 articles.
1. Oxidative Cleavage of Triethylenetetramine(trien) to Yield Diethylenetriamine(dien): Structure of the MnII/MnIII Heptanuclear Complex[Mn7(trien)2(dien)2O4(OAc)8](PF6)4·2H2O
2. High nuclearity molecular species exhibiting spin frustration: fusion of two Mn III 4O2 butterfly complexes to yield an intermediate spin ground state Mn III 7O4 complex
3. (NBu4)[Mn4O2(H2O)(O2CPh)9], a Butterfly Complex with Bound H2O, and Its Use to Prepare Octanuclear and Undecanuclear Metal Complexes
4. High-Spin Molecules: (NBun4)[Mn8O6Cl6(O2CPh)7(H2O)2] (S = 11) and [Mn9Na2O7(O2CPh)15(MeCN)2] (S = 4)
5. Feasibility of a "building-block" approach to higher nuclearity manganese/oxygen/RCO2- aggregates: directed conversion of an [Mn4O2] to an [Mn8O4] complex
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